SYNTHESIS OF NEW CHIRAL Ni(II) COMPLEXES OF SCHIFF’S BASE OF DEHYDROALANINE

Authors

  • H. H. Hambardzumyan YSU, Armenia
  • A. S. Saghiyan YSU, Armenia
  • A. A. Petrosyan YSU, Armenia
  • L. L. Manasyan YSU, Armenia
  • G. M. Mkrtchyan YSU, Armenia
  • A. A. Avetisyan YSU, Armenia
  • V. I. Maleev Nesmeyanov Institute of Organoelement Compounds, RF
  • Yu. N. Belokon' Nesmeyanov Institute of Organoelement Compounds, RF

DOI:

https://doi.org/10.46991/PYSU:B/20047.38.3.075

Keywords:

S)-N-(2-benzoylphenyl)-l-(3,4-dichlorbenzyl)pirrolydin-2-carboxamide, (S)-N-(2-(2',5'-dimethylphenyl)benzoyl)-1-benzylpirrolydin-2-carboxamide, Schifts bases, atropoisomers

Abstract

New methods for the synthesis of the chiral reagents (S)-N-(2-benzoylphenyl)-l-(3,4-dichlorbenzyl)pirrolydin-2-carboxamide (CPB) and (S)-N-(2-(2',5'-dimethylphenyl)benzoyl)-1-benzylpirrolydin-2-carboxamide (BBX) and their chiral Ni2+ complexes of Schifts bases with dehydroalanine (Ni-CPB-Δ-Ala and Ni-BBX-Δ-Ala) has been elaborated. All the complexes derived from BBX are formed as atropoisomers. These atropoisomers were isolated and subjected to spectral analysis.

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Published

2004-10-19

How to Cite

Hambardzumyan, H. H., A. S. Saghiyan, A. A. Petrosyan, L. L. Manasyan, G. M. Mkrtchyan, A. A. Avetisyan, V. I. Maleev, and Yu. N. Belokon’. 2004. “SYNTHESIS OF NEW CHIRAL Ni(II) COMPLEXES OF SCHIFF’S BASE OF DEHYDROALANINE”. Proceedings of the YSU B: Chemical and Biological Sciences 38 (3 (205):75-84. https://doi.org/10.46991/PYSU:B/20047.38.3.075.

Issue

Vol. 38 No. 3 (205) (2004)

Section

Chemistry

License

Copyright (c) 2004 Proceedings of the YSU

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