AMPEROMETRIC DETERMINATION OF PALLADIUM(II) BY N,N-DIPHENYL- AND N,N'-DIPHENYLTHIOUREAS

Authors

  • A. R. Mkrtchyan Chair of Inorganic and Analytical Chemistry, YSU, Armenia
  • G. G. Darbinyan Chair of Inorganic and Analytical Chemistry, YSU, Armenia
  • G. N. Shaposhnikova Chair of Inorganic and Analytical Chemistry, YSU, Armenia
  • H. G. Khachatryan Chair of Inorganic and Analytical Chemistry, YSU, Armenia

DOI:

https://doi.org/10.46991/PYSU:B/2005.39.2.071

Keywords:

determination of palladium, sulphuric and hydrochloric acids, amperometric titration method

Abstract

Interaction of palladium(II) with N,N-diphenyl- and N,N'-diphenylthioureas has been studied by means of amperometric titration method. Passing of the reactions has been recorded with Pd(II):R=l:2 and Pd(II):R=l:4 molar ratio between the reacted components. Determination of the palladium(II) is possible within wide concentration range of the sulphuric and hydrochloric acids. Statistical mathematical treatment of the experimental data has been carried out. Technique for amperometric determination of the palladium using the above-mentioned reagents has been elaborated and applied for its determination in the palladium-plating electrolyte.

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Published

2005-06-10

How to Cite

Mkrtchyan, A. R., G. G. Darbinyan, G. N. Shaposhnikova, and H. G. Khachatryan. 2005. “AMPEROMETRIC DETERMINATION OF PALLADIUM(II) BY N,N-DIPHENYL- AND N,N’-DIPHENYLTHIOUREAS”. Proceedings of the YSU B: Chemical and Biological Sciences 39 (2 (207):71-74. https://doi.org/10.46991/PYSU:B/2005.39.2.071.

Issue

Section

Chemistry

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