CHEMOSELECTIVITY OF AMINOMETHYLATION OF AMINO- AND ALKOXYETHANOLS IN CHARGE UNITS OF GENERAL THEORY OF ACIDS AND BASES
DOI:
https://doi.org/10.46991/PYSU:B/2016.50.3.060Keywords:
chemoselectivity, aminomethylation, acid of Pauling, base of PaulingAbstract
The evidence on the violation of chemoselectivity of aminomethylation of dimethyl- and diethylaminoethanol, which occurs under the influence of hydrogen bond was received. The same hydrogen bond occurs in the oxygen analogues of aminoethanols and β-alkoxietanols, but contrary to expectations, it is not accompanied by a change in the chemoselectivity of the reaction. We propose a rationale to explain the differences in the properties of these molecules, using charge units of the ionic character of the bond.
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2016-11-21
How to Cite
Petrosyan, K.H. 2016. “CHEMOSELECTIVITY OF AMINOMETHYLATION OF AMINO- AND ALKOXYETHANOLS IN CHARGE UNITS OF GENERAL THEORY OF ACIDS AND BASES”. Proceedings of the YSU B: Chemical and Biological Sciences 50 (3 (241):60-63. https://doi.org/10.46991/PYSU:B/2016.50.3.060.
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